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Here's a clip (17MB, 5m45) from Experiment, looking at bomb calorimetry. Why? Because it's the 1970s educational show that directly inspired the first season of Look Around You.. ^_^
Oh, I don't know - they both have their charm. ^_^ The second series was based more along the lines of Tomorrow's World (and I have a clip of that, too, but the original compression's a bit wonky - x264 puts the sound out of sync, and QuickTime Player refuses to finish. The segment on ERNIE, a computer dedicated to random number generation, was a hoot, with the proud declaration that it could generate 11,000 random ten-digit numbers in one minute =:), so they could spend more time developing the silliness.

Both series are definitely worth getting, but I'd probably also lean towards the first.